Research Topics

                                      Main Research Topics of Rolf Gleiter and Coworkers

Given are the topics, the reference numbers of reviews and key publications

 

I Spectroscopy
 
He(I) Photoelectron Spectroscopy
 
a) PE Spectra of Hydrocarbons
Topics:                             Homoaromaticity, transannular interactions, π/Walsh and π/σ interactions, propellanes, interactions between double- and triple-bonds, benzvalene, cubane.
Reviews: 90, 135, 375, 400.
Selected References: 21, 22, 30, 31, 46, 48, 58, 65, 67, 78, 80, 95, 101, 102, 114, 116, 121, 168, 169, 188, 224, 234, 257, 293, 326, 329.
 
b) PE Spectra of Molecules with Heteroatoms (O, S, P)
Topics:   Spiroconjugation, azaheterocycles, trithiapentalenes, tetrathiafulvalene, heterospiranes, peroxides, P3, P4, As3-ring systems, proton sponge, tetraphospha cubanes.
Reviews:  113, 134.
Selected References: 23, 29, 38, 53, 68, 70, 81, 82, 88, 98, 115, 140, 159, 198, 199, 210, 222, 232, 235, 237, 253, 256, 261, 294, 315, 344.
 
c) PE Spectra and Model Calculations on Organometallic Molecules
Topics: α-Metallocenylmethylium ions, beryllocene, biferrocene, bis(π-allyl)nickel, bis(π-pentadienyl)dinickel, heavy atom effects, allyl-tetracarbonyl complexes, bis(pentadienyl)iron, half open metallocenes, agostic Zr-compounds, tripeldecker complexes.
Review:  635.
Selected References: 27, 125, 142, 143, 144, 149, 152, 174, 185, 186, 195, 215, 228, 248, 263, 288, 316, 323, 331, 332, 398, 407, 456, 481, 490, 644.
 
d) UV/Vis, ESR Spectroscopy
Topics: Trithiapentalene, perpendicular π-systems, photochromism, polarized absorption spectra fluorescence.
Review: 75.
Selected References: 17, 33, 47, 49, 55, 56, 74, 76, 84, 92, 94, 118, 127, 207, 259, 441, 677.

 

II Quantum Chemical Calculations
 
1) Organic Molecules
Topics: Carbenes, cyclophanes, σ/π-coupling in stereocontrol, fragmentation, rearrangements, dimerization of alkynes, Bergman cyclization.
Reviews:  62, 129, 192, 213, 219, 298, 340.
Selected References: 12, 13, 15, 24, 35, 36, 37, 41, 48, 64, 66, 83, 96, 102, 136, 151, 153, 154, 161, 166, 173, 176, 190, 197, 200, 202, 214, 234, 238, 250, 251, 255, 291, 337, 414, 452, 634, 643, 659, 666, 672, 673, 674, 676
 
2) Chalcogen-Chalcogen-Interactions
Topics: SN rings and cages, electron rich two-, three- and four-center bonds, van der Waals bonding.
Reviews: 160, 617.
Selected References: 20, 32, 42, 100, 103, 139, 148, 162, 171, 189, 220, 230, 258, 616, 632.
(see also III, 1a).

 

III Syntheses
 
1) Alkynes
a) Syntheses and Properties of Alkynes
Topics: cyclic dialkynes, π-cages, rod like diynes, bicyclic acetylenes, butadiynes and coronands with heteroatoms and triple-bonds.
Reviews: 320, 364, 385, 400, 430, 641, 658.
Selected References: 168, 225, 240, 301, 346, 347, 358, 373, 374, 395, 419, 427, 436, 437, 461, 465, 466, 470, 474, 477, 552, 557, 565, 569, 572, 574, 576, 581, 588, 640.
 
b) Syntheses with Alkynes
(see also Synthesis of Cyclophanes and Cyclacenes)
Topics: biradicals, radialenes, prismands, cryptands, phosphinolines.
Reviews: 320, 430, 605, 619.
Selected References: 282, 290, 344, 367, 369, 379, 381, 411, 412, 417, 418, 441, 443, 445, 453, 460, 463, 505, 511, 524, 536, 572, 592, 593, 605, 615, 621, 625, 626, 660, 662, 668, 672.
   
2) Syntheses: Structures and Properties of Strained Hydrocarbons
Topics: bridged cubanes, bridged prismanes, stellenes, Cope rearrangement, π-cages.
Reviews: 375, 387, 413, 425, 440.
Selected References: 283, 295, 296, 297, 305, 327, 345, 371, 378, 380, 392, 394, 399, 401, 415, 420, 437, 450, 451, 453, 455, 457, 462, 467, 468, 485, 487, 492, 500, 560, 589, 671.
   
3) Syntheses and Properties of Cyclophanes and Cyclacenes
Topics: Superphanes, endohedral metal complexes of cyclophanes.
Reviews: 387, 472, 601, 602, 619, 650
Selected References: 15, 282, 290, 306, 308, 346, 349, 379, 381, 386, 391, 396, 442, 471, 473, 515, 521, 526, 542, 585, 600, 608, 630, 634, 638, 645, 646, 661.
   
4) Syntheses and Properties of vic. Polyketones
Topics: Tri-, tetra-, and pentaketones.
Review:   525.
Selected References: 233, 244, 260, 268, 277, 339, 363, 421, 429, 432, 438, 439, 512, 595, 648, 663.

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Letzte Änderung: 18.07.2016
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