Research Topics
Main Research Topics of Rolf Gleiter and Coworkers
Given are the topics, the reference numbers of reviews and key publications
| I Spectroscopy |
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| He(I) Photoelectron Spectroscopy | |
| a) PE Spectra of Hydrocarbons | |
| Topics: | Homoaromaticity, transannular interactions, π/Walsh and π/σ interactions, propellanes, interactions between double- and triple-bonds, benzvalene, cubane. |
| Reviews: | 90, 135, 375, 400. |
| Selected References: | 21, 22, 30, 31, 46, 48, 58, 65, 67, 78, 80, 95, 101, 102, 114, 116, 121, 168, 169, 188, 224, 234, 257, 293, 326, 329. |
| b) PE Spectra of Molecules with Heteroatoms (O, S, P) | |
| Topics: | Spiroconjugation, azaheterocycles, trithiapentalenes, tetrathiafulvalene, heterospiranes, peroxides, P3, P4, As3-ring systems, proton sponge, tetraphospha cubanes. |
| Reviews: | 113, 134. |
| Selected References: | 23, 29, 38, 53, 68, 70, 81, 82, 88, 98, 115, 140, 159, 198, 199, 210, 222, 232, 235, 237, 253, 256, 261, 294, 315, 344. |
| c) PE Spectra and Model Calculations on Organometallic Molecules | |
| Topics: | α-Metallocenylmethylium ions, beryllocene, biferrocene, bis(π-allyl)nickel, bis(π-pentadienyl)dinickel, heavy atom effects, allyl-tetracarbonyl complexes, bis(pentadienyl)iron, half open metallocenes, agostic Zr-compounds, tripeldecker complexes. |
| Review: | 635. |
| Selected References: | 27, 125, 142, 143, 144, 149, 152, 174, 185, 186, 195, 215, 228, 248, 263, 288, 316, 323, 331, 332, 398, 407, 456, 481, 490, 644. |
| d) UV/Vis, ESR Spectroscopy | |
| Topics: | Trithiapentalene, perpendicular π-systems, photochromism, polarized absorption spectra fluorescence. |
| Review: | 75. |
| Selected References: | 17, 33, 47, 49, 55, 56, 74, 76, 84, 92, 94, 118, 127, 207, 259, 441, 677. |
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| II Quantum Chemical Calculations |
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| 1) Organic Molecules | |
| Topics: | Carbenes, cyclophanes, σ/π-coupling in stereocontrol, fragmentation, rearrangements, dimerization of alkynes, Bergman cyclization. |
| Reviews: | 62, 129, 192, 213, 219, 298, 340. |
| Selected References: | 12, 13, 15, 24, 35, 36, 37, 41, 48, 64, 66, 83, 96, 102, 136, 151, 153, 154, 161, 166, 173, 176, 190, 197, 200, 202, 214, 234, 238, 250, 251, 255, 291, 337, 414, 452, 634, 643, 659, 666, 672, 673, 674, 676 |
| 2) Chalcogen-Chalcogen-Interactions | |
| Topics: | SN rings and cages, electron rich two-, three- and four-center bonds, van der Waals bonding. |
| Reviews: | 160, 617. |
| Selected References: | 20, 32, 42, 100, 103, 139, 148, 162, 171, 189, 220, 230, 258, 616, 632, 678, 679, 681, 685. (see also III, 1a). |
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| III Syntheses |
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| 1) Alkynes | |
| a) Syntheses and Properties of Alkynes | |
| Topics: | cyclic dialkynes, π-cages, rod like diynes, bicyclic acetylenes, butadiynes and coronands with heteroatoms and triple-bonds. |
| Reviews: | 320, 364, 385, 400, 430, 641, 658. |
| Selected References: | 168, 225, 240, 301, 346, 347, 358, 373, 374, 395, 419, 427, 436, 437, 461, 465, 466, 470, 474, 477, 552, 557, 565, 569, 572, 574, 576, 581, 588, 640, 682. |
| b) Syntheses with Alkynes (see also Synthesis of Cyclophanes and Cyclacenes) |
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| Topics: | biradicals, radialenes, prismands, cryptands, phosphinolines. |
| Reviews: | 320, 430, 605, 619. |
| Selected References: | 282, 290, 344, 367, 369, 379, 381, 411, 412, 417, 418, 441, 443, 445, 453, 460, 463, 505, 511, 524, 536, 572, 592, 593, 605, 615, 621, 625, 626, 660, 662, 668, 672, 683. |
| 2) Syntheses: Structures and Properties of Strained Hydrocarbons | |
| Topics: | bridged cubanes, bridged prismanes, stellenes, Cope rearrangement, π-cages. |
| Reviews: | 375, 387, 413, 425, 440. |
| Selected References: | 283, 295, 296, 297, 305, 327, 345, 371, 378, 380, 392, 394, 399, 401, 415, 420, 437, 450, 451, 453, 455, 457, 462, 467, 468, 485, 487, 492, 500, 560, 589, 671. |
| 3) Syntheses and Properties of Cyclophanes and Cyclacenes | |
| Topics: | Superphanes, endohedral metal complexes of cyclophanes. |
| Reviews: | 387, 472, 601, 602, 619, 650 |
| Selected References: | 15, 282, 290, 306, 308, 346, 349, 379, 381, 386, 391, 396, 442, 471, 473, 515, 521, 526, 542, 585, 600, 608, 630, 634, 638, 645, 646, 661. |
| 4) Syntheses and Properties of vic. Polyketones | |
| Topics: | Tri-, tetra-, and pentaketones. |
| Review: | 525. |
| Selected References: | 233, 244, 260, 268, 277, 339, 363, 421, 429, 432, 438, 439, 512, 595, 648, 663. |
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Letzte Änderung:
19.09.2019
